10/14/2002 for files of constants in: CMC1002S.TCM CMC1002E.TCM CMC1002S.CCM CMC1002E.CCM [constants.zip]
PLEASE NOTE: these constants, though from the NIST database, have been adjusted to the MAXC format of 20C 0.1N and 2nd metals constant being expressed in the [MHL]/[M][HL] form.
| HYDROGEN CONSTANTS | |||||||||||||||
| H1 | H2 | H3 | H4 | dH1 | dH2 | dH3 | dH4 | ||||||||
| ADA | 6.71 | 2.3 | 1.59 | -2.9 | |||||||||||
| AMP-5 | 6.202 | 3.854 | 0.8 | -4 | |||||||||||
| ADP | 6.374 | 3.924 | 0.6 | -4 | |||||||||||
| ATP | 6.476 | 4.039 | 0.5 | -3.6 | |||||||||||
| BAPTA | 6.372 | 5.491 | 3.26 | 2.2 | -4 | -3 | Potassium salt unless otherwise noted | ||||||||
| CITRATE | 5.696 | 4.363 | 2.919 | 0.46 | -0.75 | -1.08 | |||||||||
| DiBrBAP | 5.6 | 4.57 | 1 | 1 | =GUESS | green = checked | |||||||||
| EDTA | 10.262 | 6.186 | 2.677 | 2.004 | -5.6 | -4.2 | 1.5 | 0.3 | |||||||
| EGTA | 9.476 | 8.866 | 2.738 | 1.913 | -5.9 | -5.8 | -2.6 | -0.4 | =sodium | ||||||
| HEDTA | 9.955 | 5.423 | 2.612 | 1.6 | -6.6 | -3.1 | 1.1 | ||||||||
| NTA | 9.719 | 2.521 | 1.811 | 0.983 | -4.6 | 0.2 | 0.4 | 2 | =perchlorate | ||||||
| TPEN | 7.194 | 4.866 | 3.353 | 2.958 | -5.8 | -4.2 | -3.8 | -5.6 | |||||||
| blue = calculated | |||||||||||||||
| CHELATOR-METAL CONSTANTS | |||||||||||||||
| Al3 | Ba2 | Ca2 | Cd2 | Cu2 | Fe2 | Mg2 | Sr2 | Zn2 | Ag1 | Co2 | Fe3 | Mn2 | Ni2 | Pb2 | |
| ADA | 4.01 | 9.68 | 2.47 | 2.99 | 7.3 | 6.91 | 4.93 | 8.02 | 8.4 | ||||||
| AMP-5 | 6.17 | 1.69 | 1.825 | 3.265 | 1.895 | 1.75 | 2.72 | 2.551 | 2.35 | 2.708 | |||||
| ADP | 7.82 | 2.36 | 2.839 | 5.88 | 3.211 | 2.54 | 4.22 | 4.173 | 4.058 | 4.209 | |||||
| 4.79 | 1.34 | 1.469 | 2.62 | 1.555 | 1.41 | 2.04 | 1.89 | 2.31 | |||||||
| ATP | 7.92 | 3.18 | 3.828 | 5.32 | 6.428 | 4.143 | 3.43 | 5.169 | 4.601 | 4.764 | 4.92 | ||||
| 4.99 | 1.88 | 2.144 | 3 | 3.651 | 2.299 | 2.08 | 2.695 | 2.66 | 2.65 | 2.79 | |||||
| BAPTA | 6.97 | 1.77 | |||||||||||||
| CITRATE | 8.04 | 2.8 | 3.533 | 3.673 | 5.9 | 4.4 | 3.493 | 2.99 | 4.943 | 5 | 11.466 | 3.81 | 5.261 | 4.51 | |
| 5.16 | 1.48 | 2.09 | 2.188 | 3.593 | 2.9 | 1.854 | 1.72 | 2.978 | 3.02 | 6.7 | 2.3 | 3.214 | 3.05 | ||
| DiBrBAP | 5.96 | 1 | |||||||||||||
| EDTA | 16.254 | 7.95 | 10.734 | 16.622 | 18.89 | 14.358 | 8.755 | 8.779 | 16.566 | 6.669 | 16.509 | 25.145 | 13.955 | 18.502 | 18.172 |
| 8.652 | 3.652 | 9.269 | 11.757 | 6.84 | 2.343 | 2.447 | 9.304 | 2.417 | 9.275 | 16.183 | 6.812 | 11.366 | 10.71 | ||
| EGTA | 13.9 | 8.419 | 10.973 | 16.693 | 17.845 | 11.873 | 5.223 | 8.503 | 12.661 | 6.88 | 12.343 | 20.5 | 12.31 | 13.555 | 14.773 |
| 8.394 | 4.253 | 5.307 | 10.217 | 12.729 | 6.867 | 3.377 | 4.357 | 8.145 | 4.914 | 7.817 | 6.774 | 10.119 | 10.337 | ||
| HEDTA | 14.299 | 6.275 | 8.189 | 13.837 | 17.525 | 12.283 | 6.965 | 6.873 | 14.713 | 6.67 | 14.589 | 19.7 | 11.173 | 17.237 | 15.765 |
| 6.484 | 6.182 | 10.02 | 5.128 | 6.874 | 9.822 | 8.02 | |||||||||
| NTA | 11.6 | 4.836 | 6.465 | 9.818 | 13.03 | 8.82 | 5.454 | 5.004 | 10.67 | 5.161 | 10.38 | 15.86 | 7.448 | 11.54 | 11.53 |
| 3.781 | 4.911 | 2.442 | 7.041 | 4.261 | |||||||||||
| TPEN | 16.329 | 20.489 | 14.609 | 15.589 | 11.289 | 16.623 | 10.28 | 21.603 | 14.048 | ||||||
| dH values: | |||||||||||||||
| Al3 | Ba2 | Ca2 | Cd2 | Cu2 | Fe2 | Mg2 | Sr2 | Zn2 | Ag1 | Co2 | Fe3 | Mn2 | Ni2 | Pb2 | |
| ADA | -2 | 20.0/0.1 | 5 | -1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | ||||||
| AMP-5 | 25/0.1 | 25/0.1 | -1 | -6.2 | 1.8 | 25/0.1 | 25/0.1 | -1.1 | 2.2 | -2.4 | |||||
| ADP | 25/0.1 | 25/0.1 | 2.3 | 25/0.1 | 3.7 | 25/0.1 | 25/0.1 | 2.8 | 3.2 | 1.5 | |||||
| 25/0.1 | 25/0.1 | 1.5 | 25/0.1 | 1.8 | 25/0.1 | 25/0.1 | 25/0.1 | 25/0.1 | |||||||
| ATP | 25/0.1 | 25/0.1 | 3.2 | 25/0.1 | 0.8 | 4.4 | 25/0.1 | 3.9 | 4.5 | 4.3 | 25/0.1 | ||||
| 25/0.1 | 25/0.1 | 1.9 | 25/0.1 | -3.5 | 2.3 | 25/0.1 | 1.1 | 25/0.1 | 25/0.1 | 25/0.1 | |||||
| BAPTA | 20/0.1 | 20/0.1 | |||||||||||||
| CITRATE | 25/0.1 | 25/0.1 | -2 | 2 | 25/0.1 | 20/0.1 | 2 | 25/0.1 | 2 | 20/0.1 | -6.9 | 25/0.1 | 4 | 25/0.1 | |
| 25/0.1 | 25/0.1 | -1 | 0 | 2 | 25/0.1 | 0 | 25/0.1 | 0 | 20/0.1 | 25/0.1 | 25/0.1 | 3 | 25/0.1 | ||
| DiBrBAP | 5.53 | ||||||||||||||
| EDTA | 12.6 | -5 | -6.1 | -9.1 | -8.2 | -4 | 3.4 | -4.1 | -4.7 | -7.5 | -4.1 | -2.7 | -4.6 | -7.5 | -13.1 |
| -3.9 | 20/0.1 | -0.4 | -2 | -1 | 20/0.1 | 20/0.1 | 25/0.1 | 20/0.1 | -1.9 | -0.1 | -1.2 | -1.8 | 20/0.1 | ||
| EGTA | 25/0.1 | -8.9 | -8.4 | -14.8 | -11 | -5.2 | 5.2 | -6 | -4.3 | 20/0.1 | -2.8 | 25/0.1 | -8.2 | -3.8 | -13.2 |
| 25/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | 20/0.1 | ||
| HEDTA | 9 | -5.4 | -6.5 | -10.3 | -9.4 | -6 | 3.4 | -5.2 | -8.4 | 25/0.1 | -6.5 | 25/0.1 | -5.2 | -10.3 | -12.6 |
| 25/0.1 | 25/0.1 | 25/0.1 | -1 | 25/0.1 | 25/0.1 | 25/0.1 | |||||||||
| NTA | 25/0.1 | -1.44 | -1.36 | -4 | -1.9 | 20/0.1 | 4.3 | -0.54 | -0.9 | -6.3 | -0.1 | 3.2 | 1.3 | -2.6 | -3.8 |
| 25/0.1 | 25/0.1 | 25/0.1 | 25/0.1 | 25/0.1 | |||||||||||
| TPEN | -18.8 | -22.8 | -18 | -14.8 | -18 | -17.2 | -11.4 | -23.6 | -19.2 | ||||||